Jian-Yang Lin 1, Chun-Yu Co2 and Po-Jen Cheng2
1Graduate School of Opto-Electronics Engineering, National Yunlin University of Science and Technology, Yunlin, Taiwan 640, R.O.C.
2Graduate School of Electronic Engineering, National Yunlin University of Science and Technology, Yunlin, Taiwan 640, R.O.C.
Received:
February 14, 2007
Accepted:
April 10, 2007
Publication Date:
June 1, 2007
Download Citation:
||https://doi.org/10.6180/jase.2007.10.2.01
ABSTRACT
Carbon nanotubes (CNTs) were grown onto the SiO2/Si substrates with Ni or Fe catalyst by chemical vapor deposition (CVD). CNTs with spiral and bamboo-like structures have been observed when Fe or Ni is used as the catalyst. Both the CNT growths with the Fe and Ni catalysts are of the tip-growth mechanism. CNTs with closed tips and open tips are obtained when using Ni as the catalyst.
Keywords:
Carbon Nanotubes, Catalyst, CVD, Tip-Growth Mechanism
REFERENCES
- [1] Jinno, M., Bandow, S. and Ando, Y., “Multiwalled Carbon Nanotubes Produced by Direct Current Arc Discharge in Hydrogen Gas,” Chemical Physics Letters, Vol. 398, pp. 256259 (2004).
- [2] Cui, S., Scharff, P., Siegmund, C., Spiess, L., Romanus, H., Schawohl, J., Risch, K., Schneider, D. and Klotzer, S., “Preparation of Multiwalled Carbon Nanotubes by DC Arc Discharge under a Nitrogen Atmosphere,” Letters to the Editor/Carbon, Vol. 411, pp. 16451687 (2002).
- [3] Kingston, C. T., Jakubek, Z. J., Denommee, S. and Simard, B., “Efficient Laser Synthesis of Single-Walled Carbon Nanotubes through Laser Heating of the Condensing Vaporization Plume,” Carbon, Vol. 42, pp. 16571664 (2004).
- [4] Park, D., Kim, Y. H. and Lee, J. K., “Synthesis of Carbon Nanotubes on Metallic Substrates by a Sequential Combination of PECVD and Thermal CVD,” Carbon, Vol. 41, pp. 10251029 (2003).
- [5] Juang, Z. Y., Lai, J. F., Weng, C. H., Lee, J. H., Lai, H. J., Lai, T. S. and Tsai, C. H., “On the Kinetics of Carbon Nanotube Growth by Thermal CVD Method,” Diamond & Related Materials, Vol. 13, pp. 21402146 (2004).
- [6] Chen, M., Chen, C. M., Koo, H. S. and Chen, C. F., “Catalyzed Growth Model of Carbon Nanotubes by Microwave Plasma Chemical Vapor Deposition Using CH4 and CO2 Gas Mixtures,” Diamond & Related Materials, Vol. 12, pp. 18291835 (2003).
- [7] Jang, J. W., Lee, C. E., Lee, T. J., Lee, C. J. and Noh, S. J., “Atomic Force Microscopy of Bamboo-Dhaped Multiwalled Carbon Nanotube Structures,” Solid State Communications, Vol. 127, pp. 2932 (2003).
- [8] Lee, C. J., Park, J. H., Park, J., “Synthesis of BambooShaped Multiwalled Carbon Nanotubes Using Thermal Chemical Vapor Deposition,” Chemical Physics Letters, Vol. 323, pp. 560565 (2000).
- [9] Liu, R. M. and Ting, J. M., “Growth of Carbon Nanotubes Using Microwave Plasma-Enhanced Chemical Vapor Deposition Process,” Materials chemistry and Physics, Vol. 82, pp. 571574 (2003).