Journal of Applied Science and Engineering

Published by Tamkang University Press

1.30

Impact Factor

2.10

CiteScore

Rui Yu This email address is being protected from spambots. You need JavaScript enabled to view it.1

1Dongying Junyuan Petroleum Technology Development Company, Dongying 257300, China


 

Received: May 21, 2020
Accepted: July 22, 2020
Publication Date: December 1, 2020

 Copyright The Author(s). This is an open access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are cited.


Download Citation: ||https://doi.org/10.6180/jase.202012_23(4).0014  


ABSTRACT


One of the key technologies to improve the catalytic cracking of alkanes is the development of high-efficiency catalyst. This research prepared Co/HZSM-5 zeolites with the same metal oxide loading by ion exchange method and impregnation method respectively, and evaluated the reaction of catalysts with the fixed bed micro-reactor. The experimental results show that the n-heptane conversion ability of the catalyst prepared by ion exchange method is better than the catalyst prepared by impregnation method, the former has higher conversion level and gas product yield. However, the catalyst prepared by impregnation method has high selectivity for propylene and butane. The impregnation sequence has a great impact on the distribution of products, and the composite modification has a higher conversion capacity than the single metal modification.


Keywords: Catalytic cracking; Ion exchange method; Impregnation method; Fixed bed micro-reactor; Conversion capacity


REFERENCES


 

  1. [1]Jayaraman P., Ni, S. F., Li D., “Metal dithiolene complexes in olefin addition and purification, small molecule adsorption, H2 evolution and CO2 reduction”, Coordination Chemistry Reviews. Vol. 420, 213398 (2020).
  2. [2]Ana M., F., P., Hongyi S., Maria F. C., Armando J. L. P., et al, “Recent developments in vanadium-catalyzed olefin coordination polymerization”, Coordination Chemistry Reviews. Vol. 416, 213332 (2020).
  3. [3]Samaneh B., Abdolreza M., Fahime P., et al, “Advances in high carbon dioxide separation performance of poly (ethylene oxide)-based membranes”, Journal of Energy Chemistry. Vol. 46, pp. 30-52 (2020).
  4. [4]Roberto P., Alazne G., María L. F., et al. “Upgrading of heavy coker naphtha by means of catalytic cracking in refinery FCC unit”, Fuel Processing Technology. Vol. 205, 106454 (2020).
  5. [5]Jeong, S. M., Chae, J. H., Lee, W. H. “Study on the catalytic pyrolysis of naphtha over a KVO3/α-Al2O3 catalyst for production of light olefins”, Industrial & Engineering Chemistry Research, Vol. 40, No. 26, pp. 6081-6086 (2001).
  6. [6]Lee, W. H., Jeong, S. M., Chae, J. H., et al. “Coke formation on KVO3-B2O3/SA5203 catalysts in the catalytic pyrolysis of naphtha”, Industrial & Engineering Chemistry Research, Vol. 43, No. 8, pp. 1820-1826 (2004).
  7. [7]Reza, K., Shima, O., Ramin, K., “Catalytic cracking of light naphtha over hierarchical ZSM-5 using rice husk ash as silica source in presence of ultrasound energy:Effect of carbon nanotube content”, Advanced Powder Technology. Vol. 29, No. 9, pp. 2176-2187 (2018).
  8. [8]Akiyama, S., Mochizuki, H., Yamazaki, H., et al. “The effective silylation of external surface on H-ZSM5 with cyclic siloxane for the catalytic cracking of naphtha”, Molecular Catalysis. Vol. 433, pp.48-54 (2017).
  9. [9]Komatsu, T., Ishihara, H., Fuku, Y., et al. “Selective formation of alkenes through the cracking of n-heptane on Ca2+-exchanged ferrierite”, Applied Catalysis A: General. Vol. 214, No. 1, pp. 103-109 (2001).
  10. [10]Kotrel, S., Rosynek, M. P., Lunsford, J. H., “Intrinsic catalytic cracking activity of hexane over HZSM-5,H-βand H-Y zeolites”, The Journal of Physical Chemistry B. Vol. 103, No. 5, pp. 818-824 (1999).
  11. [11]Babitz, S. M., Williams, B. A., Mille, J. T., et al. “Monomolecular cracking of n-heptane on Y, MOR and ZSM-5 zolite”, Applied Catalysis A: General. Vol. 179, No. 1-2, pp. 71-86 (1999).
  12. [12]Reddy, J. K., Motokura, K., Koyama, T., et al. “Effect of morphology and particle size of ZSM-5 on catalytic performance for ethylene conversion and heptane cracking”, Journal of Catalysis. Vol. 289, No. 1, pp. 53-61 (2012).
  13. [13]Lercher, J. A., Rumplmayr, G., “Controlled decrease of acid strength by orthophosphoric acid on ZSM-5”, Applied Catalysis. Vol. 25, No. 1-2, pp. 215-222 (1986).
  14. [14]Mirodatos, C., Barthomeuf, D., “Cracking of n-decane on zeolite catalysts: Enhancement of light hydrocarbon formation by the zeolite field gradient”, Journal of Catalysis. Vol. 114, No. 1, pp. 121-135 (1988).
  15. [15]Pop, C., Ivanus, C., Boteanu, S., et al. “Catalytic process for preparing olefins by hydrocarbon pyrolysis”, US Patent.4172816,1979-10-30.
  16. [16]Zhu L., Zhang L., Qu H., X., et al, “A study on chemisorbed oxygen and reaction process of Fe–CuOx/ZSM-5 via ultrasonic impregnation method for low-temperature NH3-SCR”, Journal of Molecular Catalysis A: Chemical. Vol. 409, pp. 207-215(2015).
  17. [17]Wu Y., J., Zhang H., P., Yan Y., “High efficiency of phenol oxidation in a structured fixed bed over Cu-ZSM-5/PSSF prepared by ion-exchanged method”, Chemical Engineering Journal. Vol. 380, 122466(2020).
  18. [18]Wu Y., J., Zhang H. P., Yan Y., “Effect of copper ion-exchange on catalytic wet peroxide oxidation of phenol over ZSM-5 membrane”, Journal of Environmental Management. Vol. 270, 110907 (2020).
  19. [19]Komatsu, T., Ishihara, H., Fuku, Y., et al. “Selective formation of alkenes through the cracking of n-heptane on Ca2+-exchanged ferrierite”, Applied Catalysis A: General. Vol. 214, No. 1, pp. 103-109 (2001).
  20. [20]Jarvis, J., Wong. A., He. P., et al. “Catalytic aromatization of naphtha under methane environment: Effect of surface acidity and metal modification of HZSM-5”. Fuel. Vol. 223, pp. 211-221 (2018).


    



 

2.1
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